Francesco Totti scored a sublime winner for Andrea Andreazolli’s side just before the hour mark.
Napoli can now narrow the gap on Juventus to just two points if they win their game in hand.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.