The two sides came out at the Centenario Stadium in Resistencia but not for long.
The first leg in Brazil was won 2-1 by the home team thanks to a late Neymar penalty.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.