The Italian side cruised to victory with the veteran scoring after Erik Lamela had also found the target.
Silvio Piola is the all time top scorer with 274 goals, whilst Totti is on 226 after this weekend.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.