The Premier League champions elect have enquired about the services of the midfielder.
Matic has been key for Benfica in their battle to win the Portuguese title and the Europa League.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.