It took a late, late goal from Xavi to break the deadlock.
He struck a brilliant goal from the edge of the area, and there was time for an injury time own goal to wrap up the three points for Barcelona, to maintain their 100% start.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.