It took a late, late goal from Xavi to break the deadlock.
He struck a brilliant goal from the edge of the area, and there was time for an injury time own goal to wrap up the three points for Barcelona, to maintain their 100% start.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.